Just like dollars are split into cents or Bitcoin into satoshis, Ether is split into a smaller unit called Gwei. 1 Ether is equivalent to 1,000,000,000 Gwei or one billion Gwei. While Ether is like a dollar note, think of Gwei as the pennies in the world of Ethereum.
Blockchain networks like Ethereum can get quite congested with many people wanting to perform transactions. This leads to competition, and often, in order for your transaction to be processed more quickly, you may decide to pay a higher gas price, denominated in Gwei. There are numerous Ethereum gas calculators available online that can help you determine the optimal amount of Gwei you should spend.
Since Gwei is merely a denomination of Ether, when you buy Ether, you are technically buying billions of Gwei. Thus, when you own Ethereum, it means you already own a huge amount of Gwei and as such, Gwei doesn't need to be purchased separately.
In conclusion, Gwei is a key component of how much you pay for transactions on the Ethereum blockchain. It's a concept that becomes more familiar as you navigate the world of cryptocurrency.